光谱单位换算Spectroscopic unit converter
在任意一行输入数值,其余各行立即显示换算结果(高亮的那一行是你输入的)。波长是真空波长。 Type a value in any row; all other rows update at once (the highlighted row is your input). Wavelengths are vacuum wavelengths.
公式与适用条件Formulas and conditions
- E = h·ν = h·c·ν̃ = h·c/λ (ν̃ 以 m⁻¹ 计,λ 以 m 计;1 cm⁻¹ = 100 m⁻¹)(ν̃ in m⁻¹, λ in m; 1 cm⁻¹ = 100 m⁻¹)
- Emolar = NA·E (kJ/mol = J/mol ÷ 10³;kcal/mol = J/mol ÷ 4184,热化学卡)(kJ/mol = J/mol ÷ 10³; kcal/mol = J/mol ÷ 4184, thermochemical calorie)
- T = E / kB 等效温度只是能量的另一种写法(这个能量相当于多少 K 的热能 kBT),不是光源或样品的温度。The equivalent temperature is just another way to write the energy (this energy equals kBT at that temperature); it is not the temperature of a source or sample.
- λ[nm] = 10⁷ / ν̃[cm⁻¹],λ[µm] = 10⁴ / ν̃[cm⁻¹];hc/e = 1239.841984… nm·eV。
- 波长是真空波长。空气中的波长 λ空气 = λ真空/n,空气折射率 n ≈ 1.0003(随温度、气压、湿度和波长变化),可见光区两者相差约 0.03%(633 nm 处约 0.17 nm)。本工具不做折射率换算:仪器标称的空气波长要先换成真空波长。
- Wavelengths are vacuum wavelengths. The air wavelength is λair = λvac/n with n ≈ 1.0003 (depends on temperature, pressure, humidity and wavelength): about 0.03% in the visible (≈ 0.17 nm at 633 nm). This tool does not convert refractive indices: convert instrument-quoted air wavelengths to vacuum first.
- 适用范围:单光子能量、频率之间的数值对应关系。输入必须大于 0。不涉及介质色散、多普勒频移、相对论效应。kcal 指热化学卡(1 calth = 4.184 J,精确);其他定义的卡(如国际蒸汽表卡 4.1868 J)约差 0.07%。
- Scope: numerical relations between single-photon energy, frequency and wavelength. Inputs must be > 0. No dispersion, Doppler shift or relativistic effects. kcal means the thermochemical calorie (1 calth = 4.184 J, exact); other calories (e.g. 4.1868 J) differ by about 0.07%.
显示位数只是格式,结果准确度受输入精度和所用假设限制;本工具不做不确定度传递。Displayed digits are only formatting; accuracy is limited by your inputs and the assumptions used. No uncertainty propagation is done.